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Stainless Steel Grades: Types, Properties & Common Uses

Stainless steel is an iron-chromium alloy that contains anywhere from 10 to 30% chromium which gives the metal high resistance to corrosion. Although there are many grades of stainless steel only a dozen or so are used with any regularity. For example, AISI Type 304 SS, having a chromium-nickel constituent and low carbon, is popular for its good corrosion resistance, cleanability, and formability, making it popular for many everyday items such as kitchen sinks. AISI Type 316 SS, containing the alloying element molybdenum, is even more resistant to chemical attack than Type 304, making it useful for exposure to seawater, brine, sulfuric acids, and other corrosives found in the industrial environment. This article briefly discusses some of the popular grades of stainless steel as well as the settings in which these grades excel.

The principal types of stainless steels include:

Ferritic Stainless Steel

The addition of chromium (>17%) to a steel alloy stabilizes the ferritic phase of the alloy, making a material that is highly corrosion-resistant, if not exceptionally strong. It cannot be hardened through heat treatment but can be cold-worked to increase hardness. It is an inexpensive grade and is often used for kitchen equipment, architectural/ornamental applications, etc. where corrosion resistance, ductility, formability, and cost are important, and strength is not a concern.

Martensitic Stainless Steel

Adding carbon (up to 2%) to the chromium-iron alloy increases the alloy’s hardenability. Although unable to be hardened to the level of iron-carbon martensite, martensitic stainless steel can be sufficiently hardened to produce rust-resistant cutlery, surgical instruments, ball valves and seats, for example. Martensitic stainless steels tend to be used in specialty applications. AISI Type 410, for example, is used for making food-machine parts, pump shafts, etc., while Type 403 is used in high-heat applications such as turbines. Type 416 is considered free-machining and has the best machining characteristics of all the stainless steels; it is used for many turned SS parts. Martensitic stainless steel is magnetic and, with a high carbon content, difficult to weld.

Austenitic Stainless Steel

Adding nickel (8-20%) to the chromium-iron alloy produces a steel that is austenitic at room temperature, with a face-centered cubic structure that resists corrosion, and whose magnetic field is one of a soft magnet (ie, it can be magnetized in an electric field, but not permanently). These steels have relatively low carbon content, which makes them weldable. This group is the most commonly used of all the stainless steels, notably Type 302. The economical 304, sometimes called food-grade, is used for general-purpose corrosion-resistant applications where welding-related corrosion is of concern. The improved corrosion-resistant 316 is used for industrial applications and is considered the most corrosion-resistant of the austenitic stainless steels. An “L” after the grade indicates improved weldability under the harshest of welding conditions. Temperature resistance is increased by adding titanium, as in Type 321, a popular material in aerospace applications.

A relatively new grade of stainless steels, sometimes called PHSSs and carrying identifiers such as 15-5, 17-4, and 17-7 PH, are precipitation hardened. This special heat-treating process increases the metal’s resistance to stress corrosion cracking. Some of these PHSSs are austenitic, some are martensitic, and some fall somewhere in between. A-286 alloy was one of the first of the so-called superalloys.

Duplex Stainless Steel

Duplex steels have structures that combine both ferritic and austenitic phases, giving them almost twice the strength of austenitic varieties. With good corrosion resistance and weldability akin to that of austenitic stainless steel, they are used in a variety of special applications--on offshore platforms and in pressure vessels, for instance, where strength is imperative.

Stainless Steel Grades Summary

Table 1 below describes many of the AISI stainless steels, their strengths, and typical applications. Some of the steels with suffixes (L, S, etc.) have not been included, nor have many of the specialty PHSSs.

Grade Reference

Stainless Steel Type

Description of strengths, characteristics, and applications

201

Austenitic

Low nickel equivalent of 301, used in flatware

202

Austenitic

Low nickel equivalent of 302, used for kitchenware

205

Austenitic

Low work hardening, for spin forming

301

Austenitic

Higher work hardening, for trailer bodies, fasteners

302

Austenitic

General purpose grade

303

Austenitic

Free machining version of 302, for screw machining

304

Austenitic

Low carbon, economical grade, not seawater resistant but weldable

304L

Austenitic

Extra-low carbon improves resistance to post-weld corrosion

305

Austenitic

Low work hardening, for spin forming

308

Austenitic

Higher alloy content for corrosion/heat resistance, for welding rod/wire

309

Austenitic

High temperature, scale resistant, for heat exchangers

310

Austenitic

High temperature, scale resistant, for furnaces

314

Austenitic

High resistance to scale, for radiant tubes

316

Austenitic

Increased molybdenum for improved corrosion resistance in seawater

316L

Austenitic

A low carbon version of 316 for improved post-weld corrosion resistance

317

Austenitic

Improved corrosion and creep resistance over 316

321

Austenitic

High titanium version of 304 for better high-temperature performance

329

Aust-Ferritic

General corrosion resistance, like 316, with improved stress-crack resistance 

330

Austenitic

Resistant to carburization, oxidation, thermal shock, for heat-treating fixtures

347

Austenitic

A higher creep-strength version of 321, for jet engine components

348

Austenitic

Low retentivity version of 321, for nuclear service

384

Austenitic 

Low cold work hardening, for bolts, screws

403

Martensitic

Turbine grade, for steam turbine blading

405

Ferritic

Non-hardenable grade of 403

409

Martensitic

General purpose, for constructions not requiring heat treatment

410

Martensitic

General purpose, for machine parts such as shafting, auto exhausts

414

Martensitic

High hardenability, for springs

416

Martensitic

Free machining version of 410

420

Martensitic

High carbon modification of 410, for surgical instruments

422

Martensitic

High strength for temperatures to 1200°F, for turbine blades

429

Ferritic

Exhibits better weldability than 430

430

Ferritic

Chromium type, non-hardening, for annealing baskets, dishwashers

431

Martensitic

Special purpose, hardenable, for beater bars

434

Ferritic

Modified 430, for high resistance to road salts

436

Ferritic

General corrosion and heat resistant grade, for automotive trim

440A, B, C

Martensitic

Highest hardenability of the stainless steel grades, for use to create bearing balls

442

Ferritic

High temperature and scale resistance, for furnaces

446

Ferritic

High temperature and scale resistance, for intermittent use, pyrometer tubes

501

Martensitic

Heat resistant with high strength, for petrochemical equipment

502

Ferritic

Heat resistant with high ductility, for petrochemical equipment

Summary

This article presented a brief summary of the principal types of common stainless steel and common grades. For more information on additional products, consult our other guides or visit the Thomas Supplier Discovery Platform to locate potential sources of supply or view details on specific products.


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